Silver iodate

Silver iodate
Silver iodate
Names
IUPAC name
Silver(I) iodate
Systematic IUPAC name
Silver(I) iodate(V)
Other names
Argentous iodate
Identifiers
CAS Number
  • 7783-97-3 checkY
3D model (JSmol)
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ChemSpider
  • 145168 checkY
ECHA InfoCard 100.029.126 Edit this at Wikidata
EC Number
  • 232-039-6
PubChem CID
  • 165642
UNII
  • 5P7OX4VT1F checkY
CompTox Dashboard (EPA)
  • DTXSID80894883 Edit this at Wikidata
InChI
  • InChI=1S/Ag.HIO3/c;2-1(3)4/h;(H,2,3,4)/q+1;/p-1 checkY
    Key: YSVXTGDPTJIEIX-UHFFFAOYSA-M checkY
  • InChI=1/Ag.HIO3/c;2-1(3)4/h;(H,2,3,4)/q+1;/p-1
    Key: YSVXTGDPTJIEIX-REWHXWOFAH
  • [Ag+].[O-]I(=O)=O
Properties
Chemical formula
AgIO3
Molar mass 282.77 g/mol
Appearance white crystals
Odor odorless
Density 5.525 g/cm3
Melting point ~200 °C
Boiling point ~1150 °C
Solubility in water
0.003 g/100 mL (10 °C)
0.019 g/100 mL (50 °C)
Solubility product (Ksp)
3.17×10−8[1]
Solubility soluble in ammonia
Structure
orthorhombic
Hazards
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g. canola oilInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
2
1
0
Flash point Non-combustable
Related compounds
Other anions
silver iodide
silver chlorate
Other cations
sodium iodate
potassium iodate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Infobox references
Chemical compound

Silver iodate (AgIO3) is a light-sensitive, white crystal composed of silver, iodine and oxygen. Unlike most metal iodates, it is practically insoluble in water.

Production

Silver iodate can be obtained by reacting silver nitrate (AgNO3) with sodium iodate or potassium iodate. The by-product of the reaction is sodium nitrate.[2]

Alternatively, it can be created by the action of iodine in a solution of silver oxide.

Uses

Silver iodate is used to detect traces of chlorides in blood.[citation needed]

References

  1. ^ John Rumble (June 18, 2018). CRC Handbook of Chemistry and Physics (99 ed.). CRC Press. pp. 5–189. ISBN 978-1138561632.
  2. ^ Qiu, Chao; Sheng Han; Xingguo Cheng; Tianhui Ren (2005). "Distribution of Thioethers in Hydrotreated Transformer Base Oil by Oxidation and ICP-AES Analysis". Industrial & Engineering Chemistry Research. 44 (11): 4151–4155. doi:10.1021/ie048833b. Retrieved 2007-05-03. Silver nitrate reacts with iodate to form the precipitate of silver iodate, and the precipitate is transferred to silver nitrate.
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Silver(0,I)
  • Ag2F
Silver(I)
  • AgBF4
  • AgBr
  • AgBrO3
  • AgCN
  • AgCNO
  • AgCl
  • AgClO
  • AgClO2
  • AgClO3
  • AgClO4
  • AgF
  • AgI
  • AgIO3
  • AgMnO4
  • AgNO2
  • AgNO3
  • AgN3
  • Ag3N
  • AgReO4
  • AgOCN
  • AgSCN
  • AgCF3SO3
  • AgPF6
  • Ag2CO3
  • Ag2C2
  • Ag2C2O4
  • Ag2CrO4
  • Ag2Cr2O7
  • Ag2MoO4
  • Ag2O
  • Ag2S
  • Ag2SO3
  • Ag2S2O3
  • Ag2SO4
  • AgHSO4
  • Ag2Se
  • Ag2SeO3
  • Ag2Te
  • Ag3AsO4
  • Ag3PO4
  • KAg(CN)2
  • RbAg4I5
  • Ag(NH3)2OH
  • Ag2N2O2
  • Ag2WO4
Organosilver(I) compounds
  • AgC2H3O2
  • AgC22H43O2
  • CH3CH(OH)COOAg
  • C
    18
    H
    36
    AgO
    2
  • AgC4H3N2NSO2C6H4NH2
  • AgC
    11
    H
    23
    COO
  • Silver(II)
    • AgF2
    • [Ag(C5H5N)4]S2O8
    Silver(III)
    • Ag2O3
    • AgF3
    • Ag2S3
    Silver(I,III)
    • Ag4O4
    • v
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    HIO3 He
    LiIO3 Be +BO3 C (NH4)IO3
    +NO3
    O +F
    -F
    Ne
    NaIO3 Mg(IO3)2 Al(IO3)3 Si P +SO4 Cl Ar
    KIO3 Ca(IO3)2 Sc(IO3)3 Ti(IO3)4 V Cr Mn(IO3)2 Fe(IO3)2
    Fe(IO3)3
    Co(IO3)2 Ni(IO3)2 Cu(IO3)2 Zn(IO3)2 Ga(IO3)3 Ge As Se Br Kr
    RbIO3 Sr(IO3)2 Y(IO3)3 Zr(IO3)4 Nb Mo Tc Ru Rh Pd AgIO3 Cd(IO3)2 In(IO3)3 Sn(IO3)4 Sb Te I Xe
    CsIO3 Ba(IO3)2 * Lu(IO3)3 Hf(IO3)4 Ta W Re Os Ir Pt Au(IO3)3 Hg2(IO3)2
    Hg(IO3)2
    TlIO3 Pb(IO3)2 Bi(IO3)3 Po At Rn
    Fr Ra(IO3)2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
     
    * La(IO3)3 Ce(IO3)3 Pr(IO3)3 Nd(IO3)3 Pm(IO3)3 Sm(IO3)3 Eu(IO3)3 Gd(IO3)3 Tb(IO3)3 Dy(IO3)3 Ho(IO3)3 Er(IO3)3 Tm(IO3)3 Yb(IO3)3
    ** Ac Th(IO3)4 Pa U(IO3)2 Np(IO3)4 Pu(IO3)4 Am Cm Bk Cf Es Fm Md No
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