Lithium tellurite

Lithium tellurite
Identifiers
CAS Number
  • 14929-69-2 checkY
3D model (JSmol)
  • Interactive image
PubChem CID
  • 21124607
InChI
  • InChI=1S/2Li.H2O3Te/c;;1-4(2)3/h;;(H2,1,2,3)/q2*+1;/p-2
    Key: NBPOTQRWKBWQSQ-UHFFFAOYSA-L
  • [Li+].[Li+].[O-][Te](=O)[O-]
Properties
Chemical formula
Li2O3Te
Molar mass 189.48 g·mol−1
Appearance solid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound

Lithium tellurite is an inorganic compound, with the chemical formula Li2TeO3. It crystallises in the monoclinic crystal system, with space group C2/c.[1] It can be prepared by reacting lithium oxide,[2] lithium hydroxide[3] or lithium carbonate[4] with tellurium dioxide. It reacts with lithium fluoride at high temperatures in a 3:1 stoichiometric ratio to obtain Li7(TeO3)3F.[4]

References

  1. ^ Folger, F. Crystal structure of lithium tellurate(IV). Zeitschrift fuer Anorganische und Allgemeine Chemie, 1975. 411 (2): 103-110. ISSN: 0044-2313.
  2. ^ Moret, Jacques; Cachau-Herreillat, Danielle; Norbert, Alain; Maurin, Maurice. Lithium oxide-tellurium dioxide system. Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 1971. 272 (23): 1870-1873. ISSN: 0567-6541.
  3. ^ Breusov, O.N.; Revzina, T. V.; Druz, N. A. Synthesis and some properties of lithium tellurite. Zhurnal Neorganicheskoi Khimii, 1965. 10 (9): 1990-1992. ISSN: 0044-457X.
  4. ^ a b Jiang-He Feng, Chun-Li Hu, Hou-Ping Xia, Fang Kong, Jiang-Gao Mao (2017-12-04). "Li 7 (TeO 3 ) 3 F: A Lithium Fluoride Tellurite with Large Second Harmonic Generation Responses and a Short Ultraviolet Cutoff Edge". Inorganic Chemistry. 56 (23): 14697–14705. doi:10.1021/acs.inorgchem.7b02670. ISSN 0020-1669. PMID 29131609. Archived from the original on 2020-07-09. Retrieved 2021-03-19.{{cite journal}}: CS1 maint: multiple names: authors list (link)
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Lithium compounds
Inorganic (list)
  • Li2
  • LiAlCl4
  • Li1+xAlxGe2−x(PO4)3
  • LiAlH4
  • LiAlO2
  • LiAl1+xTi2−x(PO4)3
  • LiAs
  • LiAsF6
  • Li3AsO4
  • LiAt
  • Li[AuCl4]
  • LiB(C2O4)2
  • LiB(C6F5)4
  • LiBF4
  • LiBH4
  • LiBO2
  • LiB3O5
  • Li2B4O7
  • Li2TiF6
  • Li2ZrF6
  • Li2B4O7·5H2O
  • LiBSi2
  • LiBr
  • LiBr·2H2O
  • LiBrO
  • LiBrO2
  • LiBrO3
  • LiBrO4
  • Li2C2
  • LiCF3SO3
  • CH3CH(OH)COOLi
  • LiC2H2ClO2
  • LiC2H3IO2
  • Li(CH3)2N
  • LiCHO2
  • LiCH3O
  • LiC2H5O
  • LiCN
  • Li2CN2
  • LiCNO
  • Li2CO3
  • Li2C2O4
  • LiCl
  • LiCl·H2O
  • LiClO
  • LiFO
  • LiClO2
  • LiClO3
  • LiClO4
  • LiCoO2
  • Li2CrO4
  • Li2CrO4·2H2O
  • Li2Cr2O7
  • CsLiB6O10
  • LiD
  • LiF
  • Li2F
  • LiF4Al
  • Li3F6Al
  • FLiBe
  • LiFePO4
  • FLiNaK
  • LiGaH4
  • Li2GeF6
  • Li2GeO3
  • LiGe2(PO4)3
  • LiH
  • LiH2AsO4
  • Li2HAsO4
  • LiHCO3
  • Li3H(CO3)2
  • LiH2PO3
  • LiH2PO4
  • LiHSO3
  • LiHSO4
  • LiHe
  • LiI
  • LiIO
  • LiIO2
  • LiIO3
  • LiIO4
  • Li2IrO3
  • Li7La3Zr2O12
  • LiMn2O4
  • Li2MoO4
  • Li0.9Mo6O17
  • LiN3
  • Li3N
  • LiNH2
  • Li2NH
  • LiNO2
  • LiNO3
  • LiNO3·H2O
  • Li2N2O2
  • LiNa
  • Li2NaPO3
  • LiNaNO2
  • LiNbO3
  • Li2NbO3
  • LiO
  • LiO2
  • LiO3
  • Li2O
  • Li2O2
  • LiOH
  • Li3P
  • LiPF6
  • Li3PO4
  • Li2HPO3
  • Li2HPO4
  • Li3PO3
  • Li3PO4
  • Li2Po
  • Li2PtO3
  • Li2RuO3
  • Li2S
  • LiSCN
  • LiSH
  • LiSO3F
  • Li2SO3
  • Li2SO4
  • Li[SbF6]
  • Li2Se
  • Li2SeO3
  • Li2SeO4
  • LiSi
  • Li2SiF6
  • Li4SiO4
  • Li2SiO3
  • Li2Si2O5
  • LiTaO3
  • Li2Te
  • LiTe3
  • Li2TeO3
  • Li2TeO4
  • Li2TiO3
  • Li4Ti5O12
  • LiTi2(PO4)3
  • LiVO3·2H2O
  • Li3V2(PO4)3
  • Li2WO4
  • LiYF4
  • LiZr2(PO4)3
  • Li2ZrO3
Organic (soaps)
Minerals
Hypothetical
  • LixBey
  • HLiHe+
  • LiFHeO
  • LiHe2
  • (HeO)(LiF)2
  • La2/3-xLi3xTiO3He
Other Li-related
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Salts and covalent derivatives of the tellurite ion
H2TeO3 He
Li2TeO3 Be BxTexOx C N O +F Ne
Na2TeO3 Mg Al Si P S Cl Ar
K2TeO3 Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag CdTeO3 In Sn Sb +TeO4 I Xe
Cs Ba * Lu Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb
** Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No