Ammonium oxalate

Ammonium oxalate
Names
IUPAC name
Ammonium oxalate
Systematic IUPAC name
Ammonium ethanedioate
Other names
Diammonium oxalate
Identifiers
CAS Number
  • 1113-38-8 checkY
  • 6009-70-7 (monohydrate) checkY
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:91241 ☒N
ChemSpider
  • 13577 checkY
ECHA InfoCard 100.012.912 Edit this at Wikidata
PubChem CID
  • 14213
UNII
  • 0PB8MO5U0H checkY
  • L4MP14OB48 (monohydrate) checkY
CompTox Dashboard (EPA)
  • DTXSID50889443 Edit this at Wikidata
InChI
  • InChI=1S/C2H2O4.2H3N/c3-1(4)2(5)6;;/h(H,3,4)(H,5,6);2*1H3 checkY
    Key: VBIXEXWLHSRNKB-UHFFFAOYSA-N checkY
  • InChI=1S/C2H2O4.2H3N/c3-1(4)2(5)6;;/h(H,3,4)(H,5,6);2*1H3
  • [O-]C(=O)C([O-])=O.[NH4+].[NH4+]
Properties
Chemical formula
[NH4]2C2O4
Molar mass 124.096 g·mol−1
Appearance Colorless or white crystalline solid
Density 1.5 g/cm3[1]
Melting point 70 C (158 F, 343.15 K)
Solubility in water
5.20 g/(100 ml) (25 °C)[1]
Hazards
GHS labelling:
Hazard statements
H302, H312, H319
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
Chemical compound

Ammonium oxalate is a chemical compound with the chemical formula [NH4]2C2O4. Its formula is often written as (NH4)2C2O4 or (COONH4)2. It is an ammonium salt of oxalic acid. It consists of ammonium cations ([NH4]+) and oxalate anions (C2O2−4). The structure of ammonium oxalate is ([NH4]+)2[C2O4]2−. Ammonium oxalate sometimes comes as a monohydrate ([NH4]2C2O4·H2O). It is a colorless or white salt under standard conditions and is odorless and non-volatile. It occurs in many plants and vegetables.

Vertebrate

It is produced in the body of vertebrates by metabolism of glyoxylic acid or ascorbic acid. It is not metabolized but excreted in the urine.[2] It is a constituent of some types of kidney stone.[3][4] It is also found in guano.

Mineralogy

Oxammite is a natural mineral form of ammonium oxalate. This mineral is extremely rare. It is an organic mineral derived from guano.[5]

Chemistry

Ammonium oxalate is used as an analytical reagent and general reducing agent.[2] It and other oxalates are used as anticoagulants, to preserve blood outside the body.[citation needed]

Earth sciences

Acid ammonium oxalate (ammonium oxalate acidified to pH 3 with oxalic acid) is commonly employed in soil chemical analysis to extract iron and aluminium from poorly-crystalline minerals (such as ferrihydrite), iron(II)-bearing minerals (such as magnetite) and organic matter.[6][page needed]

References

  1. ^ a b John Rumble (June 18, 2018). CRC Handbook of Chemistry and Physics (99th ed.). CRC Press. pp. 4–41. ISBN 978-1138561632.
  2. ^ a b National Center for Biotechnology Information. PubChem Compound Database; CID 14213 (accessed 15 November 2016).
  3. ^ The International Pharmacopoeia, p.1292, Volume 1, World Health Organization, 2006 ISBN 92-4-156301-X.
  4. ^ N G Coley, "The collateral sciences in the work of Golding Bird (1814–1854)", Medical History, iss.4, vol.13, October 1969, pp.372.
  5. ^ "Home". mindat.org.
  6. ^ Rayment, George; Lyons, David (2011). Soil Chemical Methods - Australasia. CSIRO Publishing. ISBN 9780643101364.
  • v
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Ammonium salts
Inorganic salts
monatomic anions
  • NH4F
  • (NH4)2S
  • NH4Cl
  • (NH4)2Se
  • NH4Br
  • NH4I
oxyanions
  • NH4NO2
  • NH4NO3
  • (NH4)2CO3
  • (NH4)4UO2(CO3)2
  • (NH4)HCO3
  • NH4OCN
  • (NH4)3PO4
  • (NH4)2HPO4
  • (NH4)H2PO4
  • (NH4PO4)n(OH)2
  • NH4NaHPO4
  • (NH4)2SO3
  • (NH4)2SO4
  • (NH4)Al(SO4)2·12H2O
  • (NH4)2Fe(SO4)2·6H2O
  • NH4Fe(SO4)2·12H2O
  • NH4SO3NH2
  • (NH4)HSO4
  • (NH4)2S2O8
  • (NH4)2S2O3
  • NH4ClO3
  • NH4ClO4
  • NH4VO3
  • (NH4)2CrO4
  • (NH4)2Cr2O7
  • NH4MnO4
  • (NH4)3AsO4
  • (NH4)2MoO4
  • (NH4)6Mo7O24
  • (NH4)3Mo12PO40
  • NH4IO3
  • (NH4)2Ce(NO3)6
  • (NH4)8Ce2(SO4)8·4H2O
  • (NH4)10H2W12O42·4H2O
  • NH4ReO4
other anions
  • NH4BF4
  • NH4N3
  • NH4CN
  • (NH4)HF2
  • (NH4)3AlF6
  • (NH4)SiF6
  • (NH4)HS
  • NH4SCN
  • (NH4)2ZnCl4
  • (NH4)2MoS4
  • NH4I3
  • (NH4)2TeCl6
  • (NH4)2IrCl6
  • (NH4)2PtCl6
Organic salts
  • v
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Salts of the oxalate ion
(H2C2O4) He
Li2C2O4 BeC2O4 +BO3 +CO3 (NH4)2C2O4
+NO3
O F Ne
Na2C2O4
NaHC2O4
MgC2O4 Al Si +PO4
+PO3
+SO4 +Cl Ar
K2C2O4
KHC2O4
CaC2O4 Sc Ti V CrC2O4 MnC2O4 FeC2O4
Fe2(C2O4)3
+Fe
humboldtine
+NH4 +Na +K +K
CoC2O4 -Ni CuC2O4 Katsarosite Ga2(C2O4)3 Ge As Se Br Kr
Rb2C2O4 SrC2O4 Y2(C2O4)3 Zr Nb(HC2O4)5 Mo Tc Ru Rh Pd Ag2C2O4 CdC2O4 In2(C2O4)3 SnC2O4 Sb Te I Xe
Cs2C2O4 BaC2O4 * Lu2(C2O4)3 Hf Ta W Re Os Ir -Pt Au Hg Tl PbC2O4 Bi Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La2(C2O4)3 Ce2(C2O4)3 Pr2(C2O4)3 Nd2(C2O4)3 Pm2(C2O4)3 Sm2(C2O4)3 Eu2(C2O4)3 Gd2(C2O4)3 Tb2(C2O4)3 Dy2(C2O4)3 Ho2(C2O4)3 Er2(C2O4)3 Tm2(C2O4)3 Yb2(C2O4)3
** Ac2(C2O4)3 Th(C2O4)2 Pa UO2C2O4 Np(C2O4)2 Pu(C2O4)2 Am Cm2(C2O4)3 Bk2(C2O4)3 Cf2(C2O4)3 Es2(C2O4)3 Fm Md No